For the coolant to be where it is, I would think its had to come out from around the manifold bolts, which means the manifold is not sealing correctly around the front water crossover. It could be leaking around the thermostat housing too, although it appears from the pic that it has enough sealant.
Try torqueing the bolts down a bit tighter before you tear it apart.
I always use sealant on manifold bolts in that area.
Don't panic yet..... try the easy fixes.
Oh yeah.... check the radiator hose clamp too.
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